Simultaneous determination of fluorine and iodine in urine by ion chromatography with electrochemical pretreatment

被引：17
|
作者：
Hu, Kang Kang
Huang, Wei Xiong
Su, Yu Hua
Hu, Rong Zong [1 ]
机构：
[1] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2009年 / 20卷 / 12期
关键词：
Fluorine; Iodine; Urine; Electrochemical pretreatment; Ion chromatography; MOLECULAR ABSORPTION SPECTROMETRY; SAMPLES;
D O I：
10.1016/j.cclet.2009.05.030
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new method for the simultaneous determination of fluorine and iodine in urine by ion chromatography (IC) with electrochemical pretreatment has been developed. The pretreatment was performed in a novel electrochemical oxidation-neutralization device (EOND), in which iodide of the sample was oxidized to iodate and the alkaline digestion sample solution was neutralized. Under the optimized conditions, the limits of detection 0101), S/N = 3) were 2.5 mu g/L for fluoride and 20 mu g/L for iodate, respectively. The recoveries were in the range of 93-102% for fluoride and 86-98% for iodate. (C) 2009 Rong Zong Hu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
引用
收藏
页码：1483 / 1486
页数：4
相关论文
共 50 条
  • [41] Determination of Fluorine in the Atmosphere Surrounded the Yellow Phosphorous Enterprise Using Ion Chromatography
    Yuan, Xin
    Tian, Senlin
    Jiang, Ming
    Miao, Rongrong
    Wang, Qian
    Zhou, Jian
    SUSTAINABLE DEVELOPMENT OF URBAN AND RURAL AREAS, 2014, 507 : 773 - 776
  • [42] Simultaneous determination of six dialkylphosphates in urine by liquid chromatography tandem mass spectrometry
    Dulaurent, S
    Saint-Marcoux, F
    Marquet, P
    Lachâtre, G
    JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 2006, 831 (1-2): : 223 - 229
  • [43] DETERMINATION OF BROMIDE IN SNOW SAMPLES BY ION CHROMATOGRAPHY WITH ELECTROCHEMICAL DETECTION
    SEEFELD, S
    BALTENSPERGER, U
    ANALYTICA CHIMICA ACTA, 1993, 283 (01) : 246 - 250
  • [44] Determination of total iodine in serum and urine samples by ion chromatography with pulsed amperometric detection - Studies on analyte loss, optimization of sample preparation procedures, and validation of analytical method
    Blazewicz, Anna
    Klatka, Maria
    Dolliver, Wojciech
    Kocjan, Ryszard
    JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 2014, 962 : 141 - 146
  • [45] Spectrophotometric determination of iodine by iodine starch method in urine samples after alkaline ashing
    Divrikli, Ü
    Soylak, M
    Dogan, M
    CHEMIA ANALITYCZNA, 2000, 45 (02): : 257 - 264
  • [46] Determination of common anions in oxalate by ion chromatography coupled with UV photolysis pretreatment
    Sheng Lin Cao~a
    ChineseChemicalLetters, 2012, 23 (11) : 1263 - 1266
  • [47] Determination of common anions in oxalate by ion chromatography coupled with UV photolysis pretreatment
    Cao, Sheng Lin
    Ye, Ming Li
    Lv, Wei De
    Pan, Guang Wen
    Zhang, Ting Ting
    Hu, Zhong Yang
    Liang, Li Na
    Zhu, Yan
    CHINESE CHEMICAL LETTERS, 2012, 23 (11) : 1263 - 1266
  • [48] Rapid Simultaneous Determination of 11 Synthetic Cannabinoids in Urine by Liquid Chromatography-Triple Quadrupole Mass Spectrometry
    Wu, Jianbing
    Zhang, Fan
    Ke, Xing
    Jia, Wei
    Wan, Xuzhi
    Zhang, Lange
    Fan, Yilei
    Zhou, Jing
    SEPARATIONS, 2023, 10 (03)
  • [49] Determination of Trace Iodine in Seawater - Use of Ion Chromatography and Capillary Zone Electrophoresis -
    Ito, Kazuaki
    Takeda, Kazuhiko
    Hirokawa, Takeshi
    BUNSEKI KAGAKU, 2019, 68 (04) : 227 - 239
  • [50] Simultaneous determination of borate, chloride and molybdate in pyrohydrolysis distillates of plant and soil samples by ion chromatography
    Mishra, Vivekchandra Guruprasad
    Das, Mrinal Kanti
    Shah, Dipti Jayesh
    Jeyakumar, Subbiah
    Tomar, Bhupendra Singh
    Ramakumar, Karanam Lakshminarayana
    JOURNAL OF CHROMATOGRAPHY A, 2018, 1532 : 144 - 149
12345