Application of high-temperature gas chromatography-mass spectrometry to the investigation of glycosidically bound components related to cashew apple (Anacardium occidentale L. Var. nanum) volatiles

被引:45
作者
Bicalho, B [1 ]
Pereira, AS [1 ]
Neto, FRA [1 ]
Pinto, AC [1 ]
Rezende, CM [1 ]
机构
[1] Univ Fed Rio de Janeiro, Dept Quim Organ, Lab 621 607, Inst Quim,Ilha Fundao,Ctr Technol, BR-21949900 Rio De Janeiro, Brazil
关键词
cashew apple; Anacardium occidentals L; volatile compounds; glycoside; high-temperature gas chromatography;
D O I
10.1021/jf9909252
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
Free and bound volatile components of a Brazilian cashew apple variety (Anacardium occidentale L. var. nanum) were obtained by simultaneous distillation-extraction (SDE) and XAD-2 adsorption. According to gas chromatography-mss spectrometry (GC-MS) analyses and retention indices, 62 free volatile constituents were characterized and quantified. They were esters (40%), terpenes (20%), hydrocarbons (14%), fatty acids (9%), aldehydes (8%), alcohols (3%), lactones (3%), ketones (1%), phenols (1%), and norisoprenoids (1%). The glycosidically bound volatile precursors were analyzed by high-temperature CC-MS, after room temperature silylation. Several conjugated alcohols and cinnamic acids were detected and reported as cashew apple glycosyl constituents for the first time.
引用
收藏
页码:1167 / 1174
页数:8
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