Studies on the cracking of n-hexane over H-ZSM-48

被引:13
作者
Bhattacharya, D
Chatterjee, M
Sivasanker, S
机构
[1] National Chemical Laboratory
来源
REACTION KINETICS AND CATALYSIS LETTERS | 1997年 / 60卷 / 02期
关键词
ZSM-48; high silica zeolites; n-hexane; cracking of n-hexane; deactivation of zeolites;
D O I
10.1007/BF02475704
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The influence of various reaction parameters such as temperature, WHSV and H-2 to n-C-6 molar ratio on n-hexane cracking at atmospheric pressure over ZSM-48 has been studied. The influence of SiO2/Al2O3 variations and isomorphous substitution by Ga and Fe has also been investigated. A linear relationship between the specific catalytic activity for the cracking of n-hexane and the concentration of strong acid sites has been found.
引用
收藏
页码:395 / 403
页数:9
相关论文
共 11 条
[1]  
BHATTACHARYA D, 1996, APPL CATAL, V141, P117
[2]   ACTIVE CENTRES OVER HZSM5 ZEOLITES FOR PARAFFIN CRACKING. [J].
Borade, R.B. ;
Hegde, S.G. ;
Kulkarni, S.B. ;
Ratnasamy, P. .
Applied catalysis, 1984, 13 (01) :27-38
[3]  
Chu P., 1983, US Patent, Patent No. 4397827
[4]   CATALYTIC ACTIVITY OF LARGE-PORE HIGH SI/AL ZEOLITES - CRACKING OF HEPTANE ON H-BETA AND DEALUMINATED HY ZEOLITES [J].
CORMA, A ;
FORNES, V ;
MONTON, JB ;
ORCHILLES, AV .
JOURNAL OF CATALYSIS, 1987, 107 (02) :288-295
[5]  
HAAG WO, 1982, FARADAY GENERAL DISC, V72, P317
[6]  
JACOBS PA, 1987, STUDIES SURFACE SCI, V33, P26
[7]   PREDICTION OF CRACKING CATALYST BEHAVIOR BY A ZEOLITE UNIT-CELL SIZE MODEL [J].
PINE, LA ;
MAHER, PJ ;
WACHTER, WA .
JOURNAL OF CATALYSIS, 1984, 85 (02) :466-476
[8]  
SCHLENKER JL, 1985, ZEOLITES, V5, P555
[9]  
VALYOCSIK EW, 1984, Patent No. 0142317
[10]   CARBON FORMATION IN CATALYTIC CRACKING [J].
VOORHIES, A .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1945, 37 (04) :318-322