Synthesis and Characterization of N,N′-Carbonyl Difatty Amides from Palm Oil

被引：30

作者：

Al-Mulla, Emad A. Jaffar ^{[1
]}

Yunus, Wan Md. Zin Wan ^{[1
]}

Ibrahim, Nor Azowa Bt ^{[1
]}

Rahman, Mohd Zaki A. ^{[1
]}

机构：

[1] Univ Putra Malaysia, Fac Sci, Dept Chem, Serdang 43400, Selangor, Malaysia

来源：

JOURNAL OF OLEO SCIENCE | 2009年 / 58卷 / 09期

关键词：

palm oil; urea; Difatty amides; ethyl fatty esters; sodium ethoxide; ACID; DERIVATIVES; AMMONIOLYSIS;

D O I：

10.5650/jos.58.467

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

N,N'-Carbonyl difatty amides (CDFAs) have been synthesized from palm oil using sodium ethoxide as catalyst. Ethyl fatty esters (EFEs) were produced as a by-product as well as glycerol. The synthesis was carried out by reflux palm oil and urea in presence of ethanol. In this process, palm oil gave 79% pure CDFAs after 8 hours and molar ratio of urea to palm oil was 6.2:1 at 78 degrees C. Both CDFAs and EFEs have been characterized using elemental analysis, Fourier transform infrared (FTIR) spectroscopy and H-1 nuclear magnetic resonance (NMR) technique.

引用

页码：467 / 471

页数：5

共 19 条

[1] INVESTIGATION OF SOYBEAN OIL AS A DIESEL FUEL EXTENDER - ENDURANCE TESTS [J].

ADAMS, C ;

PETERS, JF ;

RAND, MC ;

SCHROER, BJ ;

ZIEMKE, MC .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1983, 60 (08) :1574-1579

[2] Lipase-catalysed ammoniolysis of lipids. A facile synthesis of fatty acid amides [J].

deZoete, MC ;

KockvanDalen, AC ;

vanRantwijk, F ;

Sheldon, RA .

JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 1996, 1 (3-6) :109-113

[3]

Dickey J.B., 1943, Organic Syntheses Coll, V2, P60

[4] Copper(II) complexes of acid amide derivatives of 2-aminopyridine and an exogenous ligand [J].

Garg, BS ;

Bhojak, N ;

Dwivedi, P ;

Kumar, V .

TRANSITION METAL CHEMISTRY, 1999, 24 (04) :463-466

[5] Transesterified milkweed (Asclepias) seed oil as a biodiesel fuel [J].

Holser, Ronald Alan ;

Harry-O'Kuru, Rogers .

FUEL, 2006, 85 (14-15) :2106-2110

[6] Production of a novel compound, 7,10,12-trihydroxy-8(E)octadecenoic acid from ricinoleic acid by Pseudomonas aeruginosa PR3 [J].

Kuo, TM ;

Kim, H ;

Hou, CT .

CURRENT MICROBIOLOGY, 2001, 43 (03) :198-203

[7] Lipase-catalyzed production of novel hydroxylated fatty amides in organic solvent [J].

Levinson, WE ;

Kuo, TM ;

Kurtzman, CP .

ENZYME AND MICROBIAL TECHNOLOGY, 2005, 37 (01) :126-130

[8]

Litjens MJJ, 1999, BIOTECHNOL BIOENG, V65, P347, DOI 10.1002/(SICI)1097-0290(19991105)65:3<347::AID-BIT13>3.0.CO

[9]

2-9

[10] FATTY-ACID DERIVATIVES - IMPORTANT SURFACTANTS FOR HOUSEHOLD, COSMETIC AND INDUSTRIAL PURPOSES [J].

MAAG, H .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1984, 61 (02) :259-267

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