(2,2′-Bipyridyl)bis[N,N-bis(2-hydroxyethyl)dithiocarbamato-κ2S,S′]cadmium(II)

被引：4
|
作者：
Song, Juyoung C. [2 ]
Tiekink, Edward R. T. [1 ]
机构：
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
ADDUCTS;
D O I：
10.1107/S1600536809049678
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Cd(C5H10NO2S2)(2)(C10H8N2)], features a trigonal-prismatic coordination geometry for the Cd-II ion, based on an N2S4 donor set defined by two chelating dithiocarbamate ligands and a 2,2'-bipyridyl ligand. In the crystal, extensive O-H center dot center dot center dot O hydrogen bonding results in the formation of 12-membered {center dot center dot center dot HO}(6) synthons and one-dimensional supramolecular chains with further O-H center dot center dot center dot S interactions providing additional stability to the linear chain with base vector [01(1) over bar].
引用
收藏
页码：M1667 / U1458
页数：13
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