A Nonmetal Catalyst for Molecular Hydrogen Activation with Comparable Catalytic Hydrogenation Capability to Noble Metal Catalyst

被引：143

作者：

Li, Baojun

Xu, Zheng ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 45期

基金：

中国国家自然科学基金;

关键词：

HETEROLYTIC DIHYDROGEN ACTIVATION; FRUSTRATED LEWIS PAIR; FACILE; REDUCTION; H-2; GENERATION; MECHANISM; CARBENE; IMINES;

D O I：

10.1021/ja9061097

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fullerene can activate molecular hydrogen and is a novel nonmetal hydrogenation catalyst. The hydrogenation of aromatic nitro compounds to amino aromatics is achieved on this catalyst with high conversion and selectivity under 1 atmospheric pressure of H, and light irradiation at room temperature or under conditions of 120-160 degrees C and 4-5 MPa H-2 pressure without tight irradiation, which is comparable to the case with a noble metal catalyst.

引用

页码：16380 / +

页数：5

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