Cobalt(II)-Catalyzed C-H Amination of Arenes with Simple Alkylamines

被引：97

作者：

Zhang, Lin-Bao ^{[1
]}

Zhang, Shou-Kun ^{[1
]}

Wei, Donghui ^{[1
]}

Zhu, Xinju ^{[1
]}

Hao, Xin-Qi ^{[1
]}

Su, Jian-Hang ^{[1
]}

Niu, Jun-Long ^{[1
]}

Song, Mao-Ping ^{[1
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China

来源：

ORGANIC LETTERS | 2016年 / 18卷 / 06期

关键词：

CATALYZED DIRECT AMINATION; N BOND FORMATION; INTRAMOLECULAR AMINATION; INTERMOLECULAR AMINATION; ACID-DERIVATIVES; C(SP(3))-H BONDS; TERMINAL ALKYNES; AMIDATION; ACTIVATION; ANILINES;

D O I：

10.1021/acs.orglett.6b00241

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new method of cobalt-catalyzed amination of arylamides with simple alkylamines is reported through C(sp(2))-H bond functionalization. For the first time, inexpensive cobalt is exploited as the catalyst in the amination of C(sp(2))-H bond using simple alkylamines.

引用

页码：1318 / 1321

页数：4

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