Construction of mixed-valence Cu(I)/Cu(II) 3-D framework and its photocatalytic activities

被引：7

作者：

Xu, Zhouqing ^{[1
]}

Li, Qingqing ^{[1
]}

He, Xinglei ^{[1
]}

Li, Huijun ^{[1
]}

Wang, Yuan ^{[1
]}

Cao, Jianliang ^{[1
]}

机构：

[1] Henan Polytech Univ, Coll Chem & Chem Engn, Jiaozuo 454000, Peoples R China

来源：

POLYHEDRON | 2018年 / 151卷

基金：

中国国家自然科学基金;

关键词：

Metal-organic frameworks; Crystal structure; Semiconductors; Porous materials; Photocatalytic property; PERSISTENT ORGANIC POLLUTANTS; HIGHLY EFFICIENT REMOVAL; TOXIC DYES; ADSORPTION; COMPLEXES; DEGRADATION;

D O I：

10.1016/j.poly.2018.06.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A Cu(I)/Cu(II) 3D framework, {[(CuII)(3)(CuI)(3)(pbt)(3)Cl-2]center dot ClO4 center dot H2O}(n) (HPU-3) (H(2)pbt =5'-(pyridin-2-yl)-2H,4'H-3,3'-bi(1,2,4-triazole)), has been synthesized by using solvothermal method. UV-Vis absorption spectrum indicates that HPU-3 has strong optical capability nearly in the whole range of visible light spectrum. HPU-3 photocatalyst exhibits good photocatalytic activity toward the degradation of Methylene Blue and Methyl Orange dyes. (C) 2018 Published by Elsevier Ltd.

引用

页码：478 / 482

页数：5

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