Construction of mixed-valence Cu(I)/Cu(II) 3-D framework and its photocatalytic activities

被引：7
|
作者：
Xu, Zhouqing [1 ]
Li, Qingqing [1 ]
He, Xinglei [1 ]
Li, Huijun [1 ]
Wang, Yuan [1 ]
Cao, Jianliang [1 ]
机构：
[1] Henan Polytech Univ, Coll Chem & Chem Engn, Jiaozuo 454000, Peoples R China
来源：
POLYHEDRON | 2018年 / 151卷
基金：
中国国家自然科学基金;
关键词：
Metal-organic frameworks; Crystal structure; Semiconductors; Porous materials; Photocatalytic property; PERSISTENT ORGANIC POLLUTANTS; HIGHLY EFFICIENT REMOVAL; TOXIC DYES; ADSORPTION; COMPLEXES; DEGRADATION;
D O I：
10.1016/j.poly.2018.06.012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A Cu(I)/Cu(II) 3D framework, {[(CuII)(3)(CuI)(3)(pbt)(3)Cl-2]center dot ClO4 center dot H2O}(n) (HPU-3) (H(2)pbt =5'-(pyridin-2-yl)-2H,4'H-3,3'-bi(1,2,4-triazole)), has been synthesized by using solvothermal method. UV-Vis absorption spectrum indicates that HPU-3 has strong optical capability nearly in the whole range of visible light spectrum. HPU-3 photocatalyst exhibits good photocatalytic activity toward the degradation of Methylene Blue and Methyl Orange dyes. (C) 2018 Published by Elsevier Ltd.
引用
收藏
页码：478 / 482
页数：5
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