Field-induced orthorhombic phase in relaxor-based ferroelectric single crystals Pb(Mg1/3Nb2/3)O3-PbTiO3

被引:8
作者
Guo, YP [1 ]
Luo, HS [1 ]
Xu, HQ [1 ]
Wang, PC [1 ]
Yin, ZW [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 201800, Peoples R China
关键词
lead magnesium niobate titanate; electric-field induced phase transition; metastable; dielectric properties; piezoelectric coefficients;
D O I
10.1080/00150190190028329
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A field-induced orthorhombic phase was observed on the (110)(cub) cuts in 0.68Pb(Mg1/3Nb2/3)O-3-0.32PbTiO(3) (PMNT 68/32) single crystals by using a polarizing microscope and electrical measurements. It was found that the induced monodomain orthorhombic ferroelectric state is intrinsic metastable, whose phase stability depends on the composition and poling field intensively, and it does not exhibit enhanced piezoelectricity, the piezoelectric coefficient d(33) are only about 300 pC/N. Whereas the coupling between two equivalent energy states, i.e., the rhombohedral (monoclinic) and orthorhombic phases is responsible for the high piezoelectric responses, the piezoelectric coefficient d(33) can reach up to 1600 pC/N.
引用
收藏
页码:79 / 86
页数:8
相关论文
共 17 条
  • [1] Amin A., 1985, Ferroelectrics, V65, P107, DOI 10.1080/00150198508008964
  • [2] MORPHOTROPIC PHASE-BOUNDARY IN PB(MG1/3NB2/3)O3-PBTIO3 SYSTEM
    CHOI, SW
    SHROUT, TR
    JANG, SJ
    BHALLA, AS
    [J]. MATERIALS LETTERS, 1989, 8 (6-7) : 253 - 255
  • [3] X-ray diffraction and phenomenological studies of the engineered monoclinic crystal domains in single crystal relaxor ferroelectrics
    Durbin, MK
    Hicks, JC
    Park, SE
    Shrout, TR
    [J]. JOURNAL OF APPLIED PHYSICS, 2000, 87 (11) : 8159 - 8164
  • [4] Polarization rotation mechanism for ultrahigh electromechanical response in single-crystal piezoelectrics
    Fu, HX
    Cohen, RE
    [J]. NATURE, 2000, 403 (6767) : 281 - 283
  • [5] Origin of the high piezoelectric response in PbZr1-xTixO3
    Guo, R
    Cross, LE
    Park, SE
    Noheda, B
    Cox, DE
    Shirane, G
    [J]. PHYSICAL REVIEW LETTERS, 2000, 84 (23) : 5423 - 5426
  • [6] DIELECTRIC AND PIEZOELECTRIC PROPERTIES OF 0.91PB(ZN1/3NB2/3)O3-0.09PBTIO3 SINGLE-CRYSTALS
    KUWATA, J
    UCHINO, K
    NOMURA, S
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1982, 21 (09): : 1298 - 1302
  • [7] PHASE-TRANSITIONS IN THE PB(ZN1/3NB2/3)O3-PBTIO3 SYSTEM
    KUWATA, J
    UCHINO, K
    NOMURA, S
    [J]. FERROELECTRICS, 1981, 37 (1-4) : 579 - 582
  • [8] LUO H, 1999, FERROELECTRICS, V231, P97
  • [9] Compositional homogeneity and electrical properties of lead magnesium niobate titanate single crystals grown by a modified Bridgman technique
    Luo, HS
    Xu, GS
    Xu, HQ
    Wang, PC
    Yin, ZW
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2000, 39 (9B): : 5581 - 5585
  • [10] A monoclinic ferroelectric phase in the Pb(Zr1-xTix)O3 solid solution
    Noheda, B
    Cox, DE
    Shirane, G
    Gonzalo, JA
    Cross, LE
    Park, SE
    [J]. APPLIED PHYSICS LETTERS, 1999, 74 (14) : 2059 - 2061