Effects of Na2CO3 impregnation on the catalytic activity of Mg3(PO4)2 in the gas-phase conversion of 2-hexanol and the alkylation of aniline with methanol

被引：10
作者：
Aramendía, MA [1 ]
Borau, V [1 ]
Jiménez, C [1 ]
Marinas, JM [1 ]
Romero, FJ [1 ]
机构：
[1] Univ Cordoba, Fac Sci, Dept Organ Chem, E-14004 Cordoba, Spain
来源：
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2000年 / 170卷 / 01期
关键词：
magnesium orthophosphates; heterogeneous catalysis; Na2CO3; impregnation; dehydration; dehydrogenation; alkylation; 2-hexanol; aniline; methanol;
D O I：
10.1016/S0927-7757(00)00474-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Various Na2CO3-impregnated magnesium orthophosphates have been synthesized and characterized by XRD, TGA, DRIFT and adsorption measurements. No decomposition or reaction of the carbonate at temperatures up to 773 K was observed. The textural and chemical properties of the catalysts were found to be modified by the carbonate loading. These catalysts are active in the gas-phase transformation of 2-hexanol and in the N-alkylation of aniline with methanol. The activity and selectivity of the catalysts in both reactions are related to their acid-base properties and carbonate content. (C) 1998 Elsevier Science B.V. All rights reserved.
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收藏
页码：51 / 58
页数：8
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