Metallabenzenes and valence isomers. Synthesis and characterization of a platinabenzene

被引：0
作者：
Jacob, V [1 ]
Weakley, TJR [1 ]
Haley, MM [1 ]
机构：
[1] Univ Oregon, Dept Chem, Eugene, OR 97403 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 18期
关键词：
D O I：
10.1002/1521-3773(20020916)41:18<3470::AID-ANIE3470>3.0.CO;2-4
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
No longer limited to the classical examples of osmium- and iridium-based metallaaromatics, treatment of [Pt(cod)Cl2] with a nucleophilic 3-vinylcyclopropene yields platinabenzene 1, which has been fully characterized by NMR spectroscopy and X-ray crystallography.
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页码：3470 / 3473
页数：4
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