Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol

被引：10

作者：

Wang Lei ^{[1
]}

Ge MaoFa ^{[1
]}

Wang WeiGang ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, BNLMS, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China

来源：

CHINESE SCIENCE BULLETIN | 2009年 / 54卷 / 20期

基金：

中国国家自然科学基金;

关键词：

atmosphereic chemistry; chloride atoms; unsaturated alcohols; gas-phase reaction; kinetics; GAS-PHASE REACTION; UNSATURATED ALCOHOLS; EMISSIONS; 2-METHYL-3-BUTEN-2-OL; TEMPERATURE; HYDROCARBON; ATMOSPHERE; GROWTH; CL; OH;

D O I：

10.1007/s11434-009-0439-1

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The reaction of a typical unsaturated alcohol, 3-methyl-3-buten-1-ol (MBO331), with Cl atoms, was investigated for the first time. The reaction was investigated using discharged flow-tube coupled with electron impact mass spectrometer. The experiments were performed over the temperature range of 248 K-298 K and at pressure of 1 torr in He as the bath gas. The obtained kinetic data were used to derive the Arrhenius expression: k(1) = (3.47 +/- 1.21) x 10(-11) exp[(599 +/- 69)/T] cm(3) molecule(-1) s(-1). Finally, atmospheric lifetimes of the MBO331 with respect to OH radicals, NO3 radicals and Cl atoms have been calculated and the atmospheric implications are considered briefly.

引用

页码：3808 / 3812

页数：5

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