Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol

被引：10
作者：
Wang Lei [1 ]
Ge MaoFa [1 ]
Wang WeiGang [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, BNLMS, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China
来源：
CHINESE SCIENCE BULLETIN | 2009年 / 54卷 / 20期
基金：
中国国家自然科学基金;
关键词：
atmosphereic chemistry; chloride atoms; unsaturated alcohols; gas-phase reaction; kinetics; GAS-PHASE REACTION; UNSATURATED ALCOHOLS; EMISSIONS; 2-METHYL-3-BUTEN-2-OL; TEMPERATURE; HYDROCARBON; ATMOSPHERE; GROWTH; CL; OH;
D O I：
10.1007/s11434-009-0439-1
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
The reaction of a typical unsaturated alcohol, 3-methyl-3-buten-1-ol (MBO331), with Cl atoms, was investigated for the first time. The reaction was investigated using discharged flow-tube coupled with electron impact mass spectrometer. The experiments were performed over the temperature range of 248 K-298 K and at pressure of 1 torr in He as the bath gas. The obtained kinetic data were used to derive the Arrhenius expression: k(1) = (3.47 +/- 1.21) x 10(-11) exp[(599 +/- 69)/T] cm(3) molecule(-1) s(-1). Finally, atmospheric lifetimes of the MBO331 with respect to OH radicals, NO3 radicals and Cl atoms have been calculated and the atmospheric implications are considered briefly.
引用
收藏
页码：3808 / 3812
页数：5
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