XPS characterization of supported Ziegler-Natta catalysts

被引:18
作者
Kaushik, V. K. [1 ]
Gupta, V. K.
Naik, D. G.
机构
[1] Indian Petrochem Corp Ltd, Res Ctr, Baroda 391346, Gujarat, India
[2] Reliance Ind Ltd, R&D Ctr, Surat 394510, Gujarat, India
关键词
Ziegler-Natta catalyst; propylene polymerization; ESCA; dispersion; titanium index;
D O I
10.1016/j.apsusc.2006.01.002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Surface analytical technique ESCA (electron spectrometer for chemical analysis) has been used for analysis of catalysts used in propylene polymerization. As a result of this analysis it has been shown that productivity of a catalyst can be correlated to Ti/Mg atomic ratio that indicates dispersion of titanium atoms on magnesium support. A quantitative indicator of productivity, i.e. "titanium index" has also been evaluated for studied catalysts. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:753 / 756
页数:4
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