Electrospun carbon nanofibers containing silicon particles as an energy-storage medium

被引:194
作者
Ji, Liwen [1 ]
Zhang, Xiangwu [1 ]
机构
[1] N Carolina State Univ, Dept Text Engn Chem & Sci, Fiber & Polymer Sci Program, Raleigh, NC 27695 USA
基金
美国国家科学基金会;
关键词
LITHIUM ION BATTERY; COMPOSITE ANODES; PERFORMANCE; NANOPARTICLES; NANOCOMPOSITE; INSERTION;
D O I
10.1016/j.carbon.2009.07.039
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new energy-storage material has been developed by embedding Si nanoparticles as an alloying medium in electrospun carbon nanofibers. Anodes made from these carbon/Si composite nanofibers combine the advantages of both carbon (long cycle life) and Si (high lithium-storage capacity). They exhibit good electrochemical performance in terms of large reversible capacity, relatively good capacity retention and excellent rate capability upon insertion/extraction of lithium. As a result, they are promising anode candidates for storing energy in high performance batteries. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3219 / 3226
页数:8
相关论文
共 30 条
  • [1] Modeling of disorder and X-ray diffraction in coal-based graphitic carbons
    Babu, VS
    Seehra, MS
    [J]. CARBON, 1996, 34 (10) : 1259 - 1265
  • [2] Hydrothermal carbon spheres containing silicon nanoparticles: synthesis and lithium storage performance
    Cakan, Rezan Demir
    Titirici, Maria-Magdalena
    Antonietti, Markus
    Cui, Guanglei
    Maier, Joachim
    Hu, Yong-Sheng
    [J]. CHEMICAL COMMUNICATIONS, 2008, (32) : 3759 - 3761
  • [3] High-performance lithium battery anodes using silicon nanowires
    Chan, Candace K.
    Peng, Hailin
    Liu, Gao
    McIlwrath, Kevin
    Zhang, Xiao Feng
    Huggins, Robert A.
    Cui, Yi
    [J]. NATURE NANOTECHNOLOGY, 2008, 3 (01) : 31 - 35
  • [4] Template-directed materials for rechargeable lithium-ion batteries
    Cheng, Fangyi
    Tao, Zhanliang
    Liang, Jing
    Chen, Jun
    [J]. CHEMISTRY OF MATERIALS, 2008, 20 (03) : 667 - 681
  • [5] Crystalline-Amorphous Core-Shell Silicon Nanowires for High Capacity and High Current Battery Electrodes
    Cui, Li-Feng
    Ruffo, Riccardo
    Chan, Candace K.
    Peng, Hailin
    Cui, Yi
    [J]. NANO LETTERS, 2009, 9 (01) : 491 - 495
  • [6] Nanostructured materials for electrochemical energy conversion and storage devices
    Guo, Yu-Guo
    Hu, Jin-Song
    Wan, Li-Jun
    [J]. ADVANCED MATERIALS, 2008, 20 (15) : 2878 - 2887
  • [7] Hasegawa T, 2004, CARBON, V42, P2573, DOI 10.1016/j.carbon.2004.050.50
  • [8] A new type of nano-sized silicon/carbon composite electrode for reversible lithium insertion
    Holzapfel, M
    Buqa, H
    Scheifele, W
    Novák, P
    Petrat, FM
    [J]. CHEMICAL COMMUNICATIONS, 2005, (12) : 1566 - 1568
  • [9] Superior storage performance of a Si@SiOx/C nanocomposite as anode material for lithium-ion batteries
    Hu, Yong-Sheng
    Demir-Cakan, Rezan
    Titirici, Maria-Magdalena
    Mueller, Jens-Oliver
    Schloegl, Robert
    Antonietti, Markus
    Maier, Joachim
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (09) : 1645 - 1649
  • [10] Nanomaterials for lithium ion batteries
    Jiang, Chunhai
    Hosono, Eiji
    Zhou, Haoshen
    [J]. NANO TODAY, 2006, 1 (04) : 28 - 33