Thermal- and Light-Induced Spin Crossover in Novel 2D Fe(II) Metalorganic Frameworks {Fe(4-PhPy)2[MII(CN)x]y}•sH2O: Spectroscopic, Structural, and Magnetic Studies

被引：54
作者：
Seredyuk, M. [2 ]
Gaspar, A. B. [1 ]
Ksenofontov, V. [2 ]
Verdaguer, M. [3 ]
Villain, F. [3 ]
Guetlich, P. [2 ]
机构：
[1] Univ Valencia, ICMOL, Dept Quim Inorgan, Valencia 46071, Spain
[2] Johannes Gutenberg Univ Mainz, Inst Anorgan & Analyt Chem, D-55099 Mainz, Germany
[3] Univ Paris 06, Inst Parisien Chim Mol, UMR CNRS 7201, FR CNRS 2769, F-75252 Paris 05, France
来源：
INORGANIC CHEMISTRY | 2009年 / 48卷 / 13期
关键词：
STATE CONVERSION PROCESSES; PHASE-TRANSITION; ROOM-TEMPERATURE; CRYSTAL-STRUCTURE; IRON(II); PRESSURE; BEHAVIOR; COMPLEX; DESIGN; 2-STEP;
D O I：
10.1021/ic900491r
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Five novel two-dimensional coordination polymers {Fe(4PhPy)(2)[M-II(CN)(4)]}center dot sH(2)O (4PhyPy = 4-phenylpyridine; 1: M-II = Pd, s 0; 2: M-II = Ni, s = 0; 3: M-II = Pt, s = 1) and (Fe(4PhPy)(2)[M-I(CN)(2)](2))center dot sH(2)O (4: M-I Ag, s = 1; 5: M-I = Au, s = 0.5) exhibiting thermal- and light-induced spin-crossover properties have been synthesized and characterized at various temperatures by XANES, EXAFS, PXRD, DSC (techniques), magnetic susceptibility measurements, and Mossbauer spectroscopy.
引用
收藏
页码：6130 / 6141
页数：12
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