Experimental Study for The Carbon Steel Corrosion Mitigation Effect of the Prepared Trimeric Cationic Surfactant in 1M HCl

被引：2

作者：

El Basiony, N. M. ^{[1
]}

Sadeek, S. A. ^{[2
]}

Reda, A. ^{[3
]}

Migahed, M. A. ^{[1
]}

机构：

[1] Egyptian Petr Res Inst EPRI, Cairo 11727, Egypt

[2] Zagazig Univ, Fac Sci, Dept Chem, Zagazig 44519, Egypt

[3] Qarun Petr Co QPC, Cairo, Egypt

来源：

EGYPTIAN JOURNAL OF CHEMISTRY | 2020年 / 64卷 / 04期

关键词：

Trimeric cationic surfactant; Efficiency; Langmuir adsorption isotherm; Tafel;

D O I：

10.21608/EJCHEM.2021.51558.3060

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Newly synthesized trimeric cationic surfactant namely; N,N'-(((2-(2-((1-(dodecyldimethylammonio)propan-2-yl)oxy)-2-oxoethyl)-2-hydroxysuccinyl) bis(oxy))bis(propane-2,1-diyl))bis(N,N-dimethyldodecan-1-aminium) bromide; (ADPC(12)) and its chemical structure has been certain by FTIR and 1HNMR spectroscopic analysistechniques. Gravimetric and electrochemical testes suggested the inhibition affinity of the prepared tested compound. Tafel curves suggested that the tested ADPC(12) acted as mixed-type effective inhibitor. The inhibitor efficiency increased by increasing the inhibitor concentration, reaching 90.03% at 1x10-4M. The inhibitor behavior study of ADPC(12) is returned in to its adsorption affinity and follows Langmuir adsorption isotherm. Surface morphology study verified the adsorption of ADPC(12) on X-65 steel surface. Thermodynamic activation parameters were calculated and discussed thoroughly.

引用

页码：1927 / 1939

页数：13

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