CO2 adsorption of MSU-2 synthesized by using nonionic polyethyleneoxide (PEO)-based surfactants

被引:6
作者
Lee, Xin Ying [1 ,2 ]
Chew, Thiam Leng [1 ,2 ]
Oh, Pei Ching [1 ,2 ]
Jawad, Zeinab Abbas [3 ]
Ho, Chii-Dong [4 ]
机构
[1] Univ Teknol PETRONAS, Fac Engn, Dept Chem Engn, Seri Iskandar 32610, Perak Darul Rid, Malaysia
[2] Univ Teknol PETRONAS, Inst Contaminant Management, CO2 Res Ctr CO2RES, Seri Iskandar 32610, Perak Darul Rid, Malaysia
[3] Curtin Univ Malaysia, Fac Engn & Sci, Chem Engn Dept, CDT 250, Miri 98009, Sarawak, Malaysia
[4] Tamkang Univ, Dept Chem & Mat Engn, 151 Yingzhuan Rd, New Taipei 25137, Taiwan
关键词
Adsorbent; Adsorption; CO2; capture; Mesoporous silica; MSU-2; Surfactant; MESOPOROUS SILICA; CARBON-DIOXIDE; TEMPERATURE; CAPTURE; SORBENTS; FAMILY;
D O I
10.1080/00986445.2019.1659785
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Adsorption technology is a well-established technology for CO2 removal. MSU-2 mesoporous silica appears to be very potential adsorbent for efficient CO2 gas adsorption due to its three-dimensional (3D) wormhole framework structures that are highly interconnected which is able to minimize the diffusion resistance of CO2. So far, there is no previous study reported on the CO2 adsorption of MSU-2. Thus, the current study focuses on the investigation on the synthesis of MSU-2 by using different surfactants (Triton X-100, Igepal CA-720 or Tergitol NP-9) and followed by the CO2 adsorption studies on the synthesized MSU-2. The morphology, crystallinity, functional groups, pore characteristics and pore structure of the MSU-2 synthesized were investigated. FESEM images showed that MSU-2 synthesized by using Igepal CA-720 possessed the most uniform and defined microspherical morphology compared to the MSU-2 synthesized by using the other surfactants. Besides, the MSU-2 synthesized by using Igepal CA-720 displayed the highest BET surface area of 938?m(2)/g and CO2 adsorption capacity of 0.57?mmol/g compared to the other MSU-2 samples. The obtained results showed that Igepal CA-720 is the most suitable surfactant for MSU-2 synthesis compared to the other surfactants in the current study.
引用
收藏
页码:474 / 482
页数:9
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