Continuous wave electron paramagnetic resonance spectroscopy in the investigation of the surface properties and chemical reactivity of an ionic oxide (MgO)

被引：18
|
作者：
Giamello, E
Murphy, D
Paganini, MC
机构：
来源：
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 1996年 / 115卷
关键词：
CW-EPR; magnesium oxide; metal-doped oxides; surface reactivity; surface-trapped electrons;
D O I：
10.1016/0927-7757(96)03599-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The surface reactivity of metal oxides has been studied by continuous wave electron paramagnetic resonance spectroscopy and is discussed by means of selected examples concerning magnesium oxide. In particular, the influence of external physical or chemical treatments experienced by the solid on its surface structure and reactivity is illustrated. Examples are given of the effects of progressive dehydration of the solid, doping with transition metal ions and, particularly, addition of alkali metal vapours.
引用
收藏
页码：157 / 170
页数：14
相关论文
共 50 条
  • [21] SURFACE INTERACTIONS OF NAY AND DECATIONATED Y ZEOLITES WITH NITRIC OXIDE AS DETERMINED BY ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY
    LUNSFORD, JH
    JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (12): : 4163 - &
  • [22] Vibrational and electron paramagnetic resonance properties of free and MgO supported AuCO complexes
    Giordano, L
    Carrasco, J
    Di Valentin, C
    Illas, F
    Pacchioni, G
    JOURNAL OF CHEMICAL PHYSICS, 2006, 124 (17):
  • [23] Continuous Wave Electron Paramagnetic Resonance Spectroscopy Reveals the Structural Topology and Dynamic Properties of Active Pinholin S2168 in a Lipid Bilayer
    Ahammad, Tanbir
    Drew, Daniel L., Jr.
    Sahu, Indra D.
    Serafin, Rachel A.
    Clowes, Katherine R.
    Lorigan, Gary A.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2019, 123 (38): : 8048 - 8056
  • [24] Triplet line shape simulation in continuous wave electron paramagnetic resonance experiments
    Blank, A
    Levanon, H
    CONCEPTS IN MAGNETIC RESONANCE PART A, 2005, 25A (01) : 18 - 39
  • [25] Feasibility study of superresolution continuous-wave electron paramagnetic resonance imaging
    Hirata, Hiroshi
    Wakana, Michi
    Susaki, Hitoshi
    APPLIED PHYSICS LETTERS, 2006, 88 (25)
  • [26] In vivo electron paramagnetic resonance oxymetry: Comparison of continuous wave and pulsed techniques
    Matsumoto, K
    Thirumaran, A
    Chandrika, B
    Devasahayam, N
    Cook, J
    Mitchell, J
    Subramanian, S
    Krishna, M
    FREE RADICAL BIOLOGY AND MEDICINE, 2003, 35 : S147 - S148
  • [27] Advancements and Prospects in Continuous Wave Time-resolved Electron Paramagnetic Resonance
    Zhang, Shixue
    Zhou, Shengqi
    Wu, Hao
    Guo, Xingwei
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2024, 40 (05) : 798 - 805
  • [28] Identification of universal cytochrome P450 binding modes using continuous wave electron paramagnetic resonance spectroscopy
    Blankenship, Shawna
    Lockart, Molly
    Cruce, Alex
    Bowman, Michael
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [29] CONTINUOUS WAVE MULTIQUANTUM ELECTRON-PARAMAGNETIC RESONANCE SPECTROSCOPY .3. THEORY OF INTERMODULATION SIDE-BAND
    MCHAOURAB, HS
    HYDE, JS
    JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (03): : 1786 - 1796
  • [30] An electron paramagnetic resonance investigation of paramagnetic defects in diamond films grown by chemical vapour deposition
    TalbotPonsonby, DF
    Newton, ME
    Baker, JM
    Scarsbrook, GA
    Sussmann, RS
    Wort, CJH
    JOURNAL OF PHYSICS-CONDENSED MATTER, 1996, 8 (07) : 837 - 849
12345