Formation of high-molecular weight polyaminoborane by Fe hydride catalysed dehydrocoupling of methylamine borane

被引：48
作者：
Anke, F. [1 ]
Han, D. [1 ]
Klahn, M. [1 ]
Spannenberg, A. [1 ]
Beweries, T. [1 ]
机构：
[1] Univ Rostock eV, Leibniz Inst Katalyse, Albert Einstein Str 29A, D-18059 Rostock, Germany
来源：
DALTON TRANSACTIONS | 2017年 / 46卷 / 21期
关键词：
AMMONIA-BORANE; IRON CATALYST; BORON-NITRIDE; AMINE-BORANES; TRANSITION-METAL; DEHYDROGENATION; COMPLEXES; HYDROGENATION; ADDUCTS; DEHYDROCOUPLING/DEHYDROGENATION;
D O I：
10.1039/c7dt01487b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complex [(PNHP) Fe(H)(CO)(HBH3)] (PNHP = HN(CH(2)CH(2)Pi-Pr-2)(2)) serves as a catalyst precursor for the selective dehydro-coupling of methylamine borane at room temperature, tentatively via an off-metal polymerisation pathway.
引用
收藏
页码：6843 / 6847
页数：5
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