Rapid defunctionalization of carbonyl group to methylene with polymethylhydrosiloxane-B(C6F5)3

被引：112

作者：

Chandrasekhar, S ^{[1
]}

Reddy, CR ^{[1
]}

Babu, BN ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Div Organ Chem 1, Hyderabad 500007, Andhra Pradesh, India

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 25期

关键词：

D O I：

10.1021/jo0204045

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The polymethylhydrosiloxane-B(C6F5)(3) combination is found to be a versatile carbonyl defunctionalization system under mild and rapid conditions. For the first time, B(C6F5)(3) has been used as a nonconventional Lewis acid catalyst to activate PMHS. Aromatic and aliphatic carbonyl compounds were effectively reduced to give the corresponding alkanes in high yields.

引用

页码：9080 / 9082

页数：3

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