La@C72 having a non-IPR carbon cage

被引：136

作者：

Wakahara, Takatsugu

Nikawa, Hidefumi

Kikuchi, Takashi

Nakahodo, Tsukasa

Rahman, G. M. Aminur

Tsuchiya, Takahiro

Maeda, Yutaka

Akasaka, Takeshi ^{[1
]}

Yoza, Kenji

Horn, Ernst

Yamamoto, Kazunori

Mizorogi, Naomi

Slanina, Zdenek

Nagase, Shigeru

机构：

[1] Univ Tsukuba, Ctr Tsukuba Adv Res Alliance, Tsukuba, Ibaraki 3058577, Japan

[2] Tokyo Gakugei Univ, Dept Chem, Tokyo 1848501, Japan

[3] Bruker AXS KK, Kanagawa 2210022, Japan

[4] Rikkyo Univ, Dept Chem, Tokyo 1718501, Japan

[5] Power Reactor & Nucl Fuel Dev Corp, Ibaraki 3191100, Japan

[6] Inst Mol Sci, Dept Theoret Mol Sci, Aichi 4448585, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 44期

关键词：

D O I：

10.1021/ja064751y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We show here that La@C72 has a non-IPR cage, unique electronic properties, and high reactivity by the spectroscopic and X-ray crystallographic analysis and the theoretical study. The isolation of La@C72 as a stable derivative might constitute an important stepping-stone on the way to isolation of these unknown metallofullerenes and open new material science of metallofullerenes. Copyright © 2006 American Chemical Society.

引用

页码：14228 / 14229

页数：2

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