Two photochemical pathways in competition:: matrix isolation, time-resolved and NMR studies of cis-[Ru(PMe3)4(H)2]

被引：18

作者：

Montiel-Palma, V

Perutz, RN ^{[1
]}

George, MW

Jina, OS

Sabo-Etienne, S

机构：

[1] Univ York, York YO10 5DD, N Yorkshire, England

[2] Univ Nottingham, Nottingham NG7 2RD, England

[3] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 13期

关键词：

D O I：

10.1039/b002297g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

cis-[Ru(PMe3)(4)(H)(2)] (1) reacts by two distinct photochemical pathways resulting in the formation of [Ru(PMe3)(4)] and [Ru(PMe3)(3)(H)(2)]; derivatives of these intermediates are generated in the presence of CO and Ph2SiH2.

引用

页码：1175 / 1176

页数：2

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