Synthesis and crystal structure of tert-butyl 1-(2-iodobenzoyl)cyclopent-3-ene-1-carboxylate

被引：0

作者：

Yin, Dejing ^{[1
]}

机构：

[1] Jiangnan Univ, Sch Biotechnol, Lihu Ave 1800, Wuxi, Jiangsu, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2019年 / 75卷

基金：

中国国家自然科学基金;

关键词：

crystal structure; substrate; cyclopentene ring; hydrogen bonding;

D O I：

10.1107/S2056989019011514

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

1-(2-Iodobenzoyl)-cyclopent-3-ene-1-carboxylates are novel substrates to construct bicyclo[3.2.1]octanes with antibacterial and antithrombotic activities. In this context, tert-butyl 1-(2-iodobenzoyl)-cyclopent-3-ene-1-carboxylate, C17H19IO3, was synthesized and structurally characterized. The 2-iodobenzoyl group is attached to the tertiary C atom of the cyclopent-3-ene ring. The dihedral angle between the benzene ring and the mean plane of the envelope-type cyclopent-3-ene ring is 26.0 (3)degrees. In the crystal, pairs of C-H center dot center dot center dot O hydrogen bonds link the molecules to form inversion dimers.

引用

页码：1383 / +

页数：8

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