Photophysical Properties and Redox Potentials of Photosensitizers for Organic Photoredox Transformations

被引：107
|
作者：
Wu, Yanyu [1 ]
Kim, Dooyoung [1 ]
Teets, Thomas S. [1 ]
机构：
[1] Univ Houston, Dept Chem, 3585 Cullen Blvd,Room 112, Houston, TX 77204 USA
来源：
SYNLETT | 2022年 / 33卷 / 12期
基金：
美国国家科学基金会;
关键词：
photosensitizers; photoredox catalysis; redox potentials; excited states; photophysics; photochemistry; PHOTOINDUCED ELECTRON-TRANSFER; VISIBLE-LIGHT PHOTOCATALYSIS; CYCLOMETALATED IRIDIUM PHOTOREDUCTANTS; LUMINESCENT TUNGSTEN(VI) COMPLEXES; DONOR-ACCEPTOR MOLECULES; EXCITED-STATE PROPERTIES; ELECTROGENERATED CHEMILUMINESCENCE; TRANSITION-METAL; HIGHLY EFFICIENT; CHARGE-TRANSFER;
D O I：
10.1055/a-1390-9065
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Photoredox catalysis has proven to be a powerful tool in synthetic organic chemistry. The rational design of photosensitizers with improved photocatalytic performance constitutes a major advancement in photoredox organic transformations. This review summarizes the fundamental ground-state and excited-state photophysical and electrochemical attributes of molecular photosensitizers, which are important determinants of their photocatalytic reactivity.
引用
收藏
页码：1154 / 1179
页数：26
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