The first general method for the synthesis of transition-metal π complexes of an electronically diverse family of 1,2-azaborolyls

被引：36
|
作者：
Liu, SY [1 ]
Hills, ID [1 ]
Fu, GC [1 ]
机构：
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
来源：
ORGANOMETALLICS | 2002年 / 21卷 / 21期
关键词：
D O I：
10.1021/om020533b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A general method for the synthesis of new families of transition-metal-free 1,2-azaborolides'(3) has been developed, based on a readily available precursor (1). These azaborolides react with a variety of transition-metal electrophiles to produce an unprecedented array of eta(5)-azaborolyl adducts (4) (substituents bound to boron: nitrogen, oxygen, hydrogen, carbon, and phosphorus).
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页码：4323 / 4325
页数：3
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