Short-range order and fractal cluster structure of aggregates of barium titanate microparticles in a composite based on cyano-ethyl ester of polyvinyl alcohol

被引:6
|
作者
Krasovskii, A. N. [1 ]
Novikov, D. V. [2 ]
Vasina, E. S. [3 ]
Matveichikova, P. V. [3 ]
Sychev, M. M. [3 ]
Rozhkova, N. N. [4 ]
机构
[1] Russian Acad Sci, Inst Analyt Instrumentat, St Petersburg 198095, Russia
[2] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia
[3] Tech Univ, St Petersburg State Technol Inst, St Petersburg 190013, Russia
[4] Russian Acad Sci, Karelian Res Ctr, Inst Geol, Petrozavodsk 185035, Republic Of Kar, Russia
基金
俄罗斯基础研究基金会;
关键词
DIELECTRIC CHARACTERISTICS; SURFACE; POLYMER; CARBON; ACID;
D O I
10.1134/S1063783415120227
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The distribution of barium titanate (BaTiO3) microparticles in the matrix of cyano-ethyl ester of polyvinyl alcohol and the change in the surface energy upon introduction of shungite carbon nanoclusters into the dielectric composite have been investigated using the methods of scanning electron microscopy and contact angles. The computer processing of the electron microscopy data has demonstrated that the introduction of 0.04% shungite carbon nanoparticles into the composite leads to a decrease in the spatial homogeneity of the quasi-lattice and to an increase in the local density distribution of BaTiO3 microparticles, as well as in the correlation length corresponding to the formation of an infinite cluster of BaTiO3 particles. It has been found that, in this case, the surface energy and dielectric permittivity of the composite extremely increase.
引用
收藏
页码:2555 / 2561
页数:7
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    A. N. Krasovskii
    D. V. Novikov
    E. S. Vasina
    P. V. Matveichikova
    M. M. Sychev
    N. N. Rozhkova
    Physics of the Solid State, 2015, 57 : 2555 - 2561
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