Short-range order and fractal cluster structure of aggregates of barium titanate microparticles in a composite based on cyano-ethyl ester of polyvinyl alcohol
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作者:
Krasovskii, A. N.
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Russian Acad Sci, Inst Analyt Instrumentat, St Petersburg 198095, RussiaRussian Acad Sci, Inst Analyt Instrumentat, St Petersburg 198095, Russia
Krasovskii, A. N.
[1
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Novikov, D. V.
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Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, RussiaRussian Acad Sci, Inst Analyt Instrumentat, St Petersburg 198095, Russia
Novikov, D. V.
[2
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Vasina, E. S.
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Tech Univ, St Petersburg State Technol Inst, St Petersburg 190013, RussiaRussian Acad Sci, Inst Analyt Instrumentat, St Petersburg 198095, Russia
Vasina, E. S.
[3
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Matveichikova, P. V.
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Tech Univ, St Petersburg State Technol Inst, St Petersburg 190013, RussiaRussian Acad Sci, Inst Analyt Instrumentat, St Petersburg 198095, Russia
Matveichikova, P. V.
[3
]
Sychev, M. M.
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Tech Univ, St Petersburg State Technol Inst, St Petersburg 190013, RussiaRussian Acad Sci, Inst Analyt Instrumentat, St Petersburg 198095, Russia
Sychev, M. M.
[3
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Rozhkova, N. N.
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Russian Acad Sci, Karelian Res Ctr, Inst Geol, Petrozavodsk 185035, Republic Of Kar, RussiaRussian Acad Sci, Inst Analyt Instrumentat, St Petersburg 198095, Russia
Rozhkova, N. N.
[4
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机构:
[1] Russian Acad Sci, Inst Analyt Instrumentat, St Petersburg 198095, Russia
[2] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia
[3] Tech Univ, St Petersburg State Technol Inst, St Petersburg 190013, Russia
[4] Russian Acad Sci, Karelian Res Ctr, Inst Geol, Petrozavodsk 185035, Republic Of Kar, Russia
The distribution of barium titanate (BaTiO3) microparticles in the matrix of cyano-ethyl ester of polyvinyl alcohol and the change in the surface energy upon introduction of shungite carbon nanoclusters into the dielectric composite have been investigated using the methods of scanning electron microscopy and contact angles. The computer processing of the electron microscopy data has demonstrated that the introduction of 0.04% shungite carbon nanoparticles into the composite leads to a decrease in the spatial homogeneity of the quasi-lattice and to an increase in the local density distribution of BaTiO3 microparticles, as well as in the correlation length corresponding to the formation of an infinite cluster of BaTiO3 particles. It has been found that, in this case, the surface energy and dielectric permittivity of the composite extremely increase.