Synthesis of enantiomerically pure cyclopropyl trifluoroborates

被引：39

作者：

Hohn, Erwin ^{[1
]}

Pietruszka, Joerg ^{[1
]}

Solduga, Gemma ^{[1
]}

机构：

[1] Univ Dusseldorf, Forschungszentrum, Inst Bioorgan Chem, D-52426 Julich, Germany

来源：

SYNLETT | 2006年 / 10期

关键词：

boron; stereoselectivity; protecting groups; cyclopropanes; cross-coupling;

D O I：

10.1055/s-2006-944185

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantiomerically pure cyclopropylboronic esters were converted to the corresponding trifluoroborates, versatile intermediates for a variety of transformations. The new deprotection conditions allowed the utilization of general building blocks for cyclopropyl amines.

引用

页码：1531 / 1534

页数：4

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