A simple method to prepare solid nanoparticles of water-soluble salts using water-in-oil microemulsions

被引:34
作者
Marcianò, V
Minore, A
Liveri, VT
机构
[1] Univ Palermo, Dipartimento Chim Fis, I-90128 Palermo, Italy
[2] Univ Palermo, Policlin Univ P Giaccone, Dipartimento Sci Chirurg & Anat, I-90128 Palermo, Italy
关键词
water-soluble inorganic salts; nanoparticles; water-in-oil microemulsions;
D O I
10.1007/s003960050039
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new and simple method to prepare solid nanoparticles of water-soluble salts using water-in-oil microemulsions is described. In particular, starting from water/sodium bis(2-ethylhexyl)sulfosuccinate/n-heptane microemulsions carrying inside the aqueous core of the reversed micelles some water-soluble salts [CaCl2, Na2HPO4, Cu(NO3)(2)], after evaporation of the volatile components (water and apolar organic solvent), the resulting inorganic salt/surfactant composites were found to be totally dispersible in pure n-heptane. The presence of nanoparticles in these resuspended composites was ascertained by transmission electron microscopy observation of samples obtained by gentle evaporation of the organic solvent.
引用
收藏
页码:250 / 252
页数:3
相关论文
共 8 条
  • [1] Calorimetric investigation of the formation of ZnS nanoparticles in W/O microemulsions
    Arcoleo, V
    Goffredi, M
    Liveri, VT
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 1998, 51 (01): : 125 - 133
  • [2] AFM investigation of gold nanoparticles synthesized in water/AOT/n-heptane microemulsions
    Arcoleo, V
    Liveri, VT
    [J]. CHEMICAL PHYSICS LETTERS, 1996, 258 (1-2) : 223 - 227
  • [3] Colloidal calcium hydroxide in organic medium: Synthesis and analysis
    Delfort, B
    Born, M
    Chive, A
    Barre, L
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1997, 189 (01) : 151 - 157
  • [4] DIDIO E, 1998, MATER ENG, V9, P67
  • [5] ATOMIC AND MOLECULAR CLUSTERS IN MEMBRANE MIMETIC CHEMISTRY
    FENDLER, JH
    [J]. CHEMICAL REVIEWS, 1987, 87 (05) : 877 - 899
  • [6] THE KINETICS OF SOLUBILISATE EXCHANGE BETWEEN WATER DROPLETS OF A WATER-IN-OIL MICROEMULSION
    FLETCHER, PDI
    HOWE, AM
    ROBINSON, BH
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1987, 83 : 985 - 1006
  • [7] STRUCTURE OF 3-COMPONENT MICROEMULSIONS IN THE CRITICAL REGION DETERMINED BY SMALL-ANGLE NEUTRON-SCATTERING
    KOTLARCHYK, M
    CHEN, SH
    HUANG, JS
    KIM, MW
    [J]. PHYSICAL REVIEW A, 1984, 29 (04): : 2054 - 2069
  • [8] Nanosized particles made in colloidal assemblies
    Pileni, MP
    [J]. LANGMUIR, 1997, 13 (13) : 3266 - 3276