catena-Poly[[bis(N-ethylethylenediamine-κ2N,N′)copper(II)]-μ-cyanido-κ2N:C-[dicyanido-κ2C-palladium(II)]-μ-cyanido-κ2C:N]

被引：3

作者：

Akitsu, Takashiro ^{[1
]}

Endo, Yuki ^{[1
]}

机构：

[1] Tokyo Univ Sci, Fac Sci, Dept Chem, Shinjuku Ku, Tokyo 1628601, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

ONE-DIMENSIONAL STRUCTURE; MAGNETIC-PROPERTIES; COORDINATION POLYMER; CRYSTAL-STRUCTURE; COMPLEXES; 1,2-DIAMINOETHANE; EN;

D O I：

10.1107/S160053680900885X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [CuPd(CN)(4)(C4H12N2)(2)](n), consists of one-dimensional chains. The Cu and Pd atoms are both located on centers of symmetry in an alternating array of [Cu(N-Eten)(2)](2+) (N-Eten = N-ethylethylenediamine) and [Pd(CN)(4)](2-) units. The Pd-C distances of 1.991 (3) and 1.992 (3) angstrom are intermediate values compared with the analogous Ni-II and Pt-II complexes [Akitsu & Einaga (2007). Inorg. Chim. Acta, 360, 497-505]. Due to Jahn-Teller effects, the axial Cu-N bond distance of 2.548 (2) angstrom is noticeably longer than the equatorial distances [Cu-NH2 = 2.007 (2) and Cu-NHC2H5 = 2.050 (2) angstrom]. There are interchain hybrogen bonds, with N(-H)center dot center dot center dot N = 3.099(4) angstrom.

引用

页码：M406 / U582

页数：10

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