The organic chemistry of poly(1H-pyrazol-1-yl)methanes

被引：39

作者：

Alkorta, Ibon ^{[1
]}

Claramunt, Rosa M. ^{[2
]}

Diez-Barra, Enrique ^{[3
]}

Elguero, Jose ^{[1
]}

de la Hoz, Antonio ^{[3
]}

Lopez, Concepcion ^{[2
]}

机构：

[1] CSIC, Inst Quim Med, Juan Cierva 3, E-28006 Madrid, Spain

[2] UNED, Fac Ciencias, Dept Quim Organ & Bioorgan, Paseo Senda Rey 9, E-28040 Madrid, Spain

[3] Univ Castilla La Mancha, Fac Ciencias & Tecnol Quim, Dept Quim Organ, Avda Camilo Jose Cela 10, E-13071 Ciudad Real, Spain

来源：

COORDINATION CHEMISTRY REVIEWS | 2017年 / 339卷

关键词：

Pyrazoles; Pyrazolylmethanes; Bis(1H-pyrazol-1-yl)methanes; Tris(1H-pyrazol-1-yl)methanes; Tetrakis(1H-pyrazol-1-yl)methanes; Metal ligands; X-ray structures; TRANSITION-METAL-COMPLEXES; SILVER(I) TRIFLUOROMETHANESULFONATE COMPLEXES; CARBONIC-ANHYDRASE ACTIVATORS; RELEVANT SCORPIONATE LIGANDS; RING-OPENING POLYMERIZATION; STRUCTURAL-CHARACTERIZATION; HETEROSCORPIONATE LIGANDS; CRYSTAL-STRUCTURES; COORDINATION CHEMISTRY; PHASE-TRANSFER;

D O I：

10.1016/j.ccr.2017.03.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Since their first synthesis by Huckel (1937) and the first systematic exploration by Trofimenko (1970), interest in poly(1H-pyrazol-1-yl)methanes (bis, tris and tetrakis) has increased dramatically. This review focuses on the synthesis and reactivity of these ligands and contains 541 different structures and 269 references. After a brief historical introduction, the synthesis, reactivity, and nature of the coordinated metals are described along with some properties of these compounds, particularly the complete set of X-ray molecular structures. All of the formulae are represented to show the extraordinary richness of poly(1H-pyrazol-1-yl) methanes and to promote the use of the already known poly(1H-pyrazol-1-yl) methanes in coordination chemistry and the design of new ligands with the reported procedures. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：153 / 182

页数：30

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