V-MCM-41 as selective catalyst for epoxidation of olefins and trans-2-hexene-1-ol

被引：28
|
作者：
Farzaneh, F [1 ]
Zamanifar, E
Williams, CD
机构：
[1] Univ Alzahra, Dept Chem, Tehran, Iran
[2] Wolverhampton Univ, Sch Appl Sci, Wolverhampton WV1 1SB, England
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 218卷 / 02期
关键词：
V-MCM-41; epoxidation; olefins; trans-2-hexene-1-ol;
D O I：
10.1016/j.molcata.2004.03.046
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Vanadium containing MCM-41(V-MCM-41) was synthesized by one pot synthesis and characterized by spectroscopic techniques. The oxidation of olefins such as 1-hexene, cyclohexene, cyclopentene, norbomene and trans-2-hexene-1-ol with tertiary butyl hydroperoxide (TBHP) in the presence of V-MCM-41 as catalyst in different solvents(CH2Cl2, CH3CN, (CH3OHCHCl3)-C-.) is described. It was found that V-MCM-41 in refluxing CHCl3 was very reactive for epoxidation of trans-2-hexene-1-ol with 52% reactivity and 100% selectivity. Oxidation of trans-2-hexene-1-ol to the corresponding epoxide in the absence of solvent was successfully carried out with the enhancement of reactivity to 94%. (C) 2004 Published by Elsevier B.V.
引用
收藏
页码：203 / 209
页数：7
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