Superhydrophobic wood fabricated by epoxy/Cu2(OH)3Cl NPs/stearic acid with performance of desirable self-cleaning, anti-mold, dimensional stability, mechanical and chemical durability

被引:27
|
作者
Lu, Quanxiong [1 ,2 ]
Cheng, Ruifeng [1 ,2 ]
Jiang, Haiqiu [1 ,2 ]
Xia, Sengwei [1 ,2 ]
Zhan, Ke [3 ]
Yi, Tengfei [4 ]
Morrell, Jeffrey J. [4 ]
Yang, Long [1 ,2 ]
Wan, Hui [1 ,2 ]
Du, Guanben [1 ,2 ]
Gao, Wei [1 ,2 ]
机构
[1] Southwest Forestry Univ, Yunnan Key Lab Wood Adhes & Glue Prod, Kunming 650224, Yunnan, Peoples R China
[2] Southwest Forestry Univ, Coll Mat Sci & Engn, Kunming 650224, Yunnan, Peoples R China
[3] Auburn Univ, Sch Forestry & Wildlife Sci, Duncan Dr, Auburn, AL USA
[4] Univ Sunshine Coast, Natl Ctr Timber Durabil & Design Life, Brisbane, Qld, Australia
关键词
Superhydrophobic wood; Copper chloride hydroxides; Anti-mold; Dimensional stability; Self-cleaning; OIL-WATER SEPARATION; SURFACE; COMPOSITE; ROBUST; PDMS;
D O I
10.1016/j.colsurfa.2022.129162
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Pinus wood (Pinus sylvestris var. mongolica Litv.) was modified to make it superhydrophobic by a simple hydrothermal method for in-situ synthesis Cu-2(OH)(3)Cl nanoparticles (NPs) followed by impregnation with a stearic acid/epoxy resin (STA/EP) ethanol solution. Surface microstructure, roughness and chemical constituents of the modified wood were characterized by scanning electron microscopy (SEM), 3D confocal microscope profilometry, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Modified wood exhibited super hydrophobicity, characterized by a static water contact angle (WCA) reach 151 +/- 3(?) and sliding angle (SA) less than 6 +/- 3(?). The modified wood remained superhydrophobicity under harsh conditions including impregnation with strong acid or alkali, 7 cycles of sandpaper abrasion, 200 cycles of tape paste, 192 h of UV irradiation and exposed at 140 ?. The modified wood also exhibited excellent functions, including anti-mold, dimensional stability, stain resistance and self-cleaning, which suggested that the process has potential for protecting wood in exterior exposures.
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页数:11
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