Crystal structure of (2,2'-bipyrimidine)-dinitratopalladium(II) acetone solvate

被引：2
|
作者：
Hudgens, T [1 ]
Johnson, D [1 ]
Cordes, W [1 ]
Barclay, T [1 ]
Jeter, D [1 ]
机构：
[1] UNIV ARKANSAS,DEPT CHEM & BIOCHEM,FAYETTEVILLE,AR 72701
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1997年 / 27卷 / 04期
基金：
美国国家科学基金会;
关键词：
palladium; bipyrimidine; nitrate; square planar; structure;
D O I：
10.1007/BF02575963
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
(2,2'-bipyrimidine)dinitratopalladium(II forms a triclinic crystal in space group P (1) over bar with a = 7.605(5) Angstrom, b = 8.791(4) Angstrom, c = 12.632(5) Angstrom, alpha = 85.11(3)degrees, beta = 78.79(4)degrees, gamma = 77.45(4)degrees, V = 807.7(7) Angstrom 3, and Z = 2. The Pd atom exhibits square planar coordination geometry with mean Pd-O = 2.206(7) Angstrom, Pd-N = 1.990(5) Angstrom, O-Pd-O = 92.0(2)degrees, and N-Pd-N = 81.0(2)degrees. The complexes associate across an inversion center with Pd ... Pd = 3.190(2) Angstrom. The bipyrimidine ligand is bowed with a 5.9(2)degrees dihedral angle between the C4N2 rings. The nitrate ions are on the same side of the N2O2 donor atoms plane and make 60.4(2)degrees and 66.6(2)degrees dihedral angles with that plane.
引用
收藏
页码：247 / 250
页数：4
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