Effect of medium solvent ratios on morphologies and optical properties of α-ZnMoO4, β-ZnMoO4 and ZnMoO4.0.8H2O crystals synthesized by microwave-hydrothermal/solvothermal method

被引：46

作者：

Keereeta, Yanee ^{[1
]}

Thongtem, Titipun ^{[2
,3
]}

Thongtem, Somchai ^{[1
,3
]}

机构：

[1] Chiang Mai Univ, Fac Sci, Dept Phys & Mat Sci, Chiang Mai 50200, Thailand

[2] Chiang Mai Univ, Fac Sci, Dept Chem, Chiang Mai 50200, Thailand

[3] Chiang Mai Univ, Fac Sci, Mat Sci Res Ctr, Chiang Mai 50200, Thailand

来源：

SUPERLATTICES AND MICROSTRUCTURES | 2014年 / 69卷

关键词：

alpha-ZnMoO4; beta-znMoO(4); ZnMoO4.0.8H(2)O; X-ray diffraction; Electron microscopy; Spectroscopy; NANOFIBERS; MOLYBDATES; ROUTE; ZN;

D O I：

10.1016/j.spmi.2014.02.011

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

ZnMoO4 with different morphologies were successfully synthesized by microwave hydrothermal and microwave solvothermal methods, without the use of any additives. The different crystalline phases (alpha-ZnMoO4, beta-ZnMoO4 and ZnMoO4.0.8H(2)O), morphologies and optical properties of the samples were studied by X-ray diffraction, electron microscopy and spectroscopy, and were found to be influenced by the length of reaction time and the different volume ratios of ethylene glycol (EG) to water as medium solvents. In this research, the direct energy gap (E-g) and photonic emission wavelength were evaluated to be 3.13-3.51 eV and 366 nm, respectively. (C) 2014 Published by Elsevier Ltd.

引用

页码：253 / 264

页数：12

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