Pr3+-Doped β-NaYF4 for Temperature Sensing with Fluorescence Intensity Ratio Technique

被引:95
作者
Zhou, Shaoshuai [1 ]
Jiang, Guicheng [1 ]
Wei, Xiantao [1 ]
Duan, Changkui [1 ]
Chen, Yonghu [1 ]
Yin, Min [1 ]
机构
[1] Univ Sci & Technol China, Dept Phys, Hefei 230026, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
Temperature Sensing; Fluorescence Intensity Ratio; Temperature Sensitivity; Hydrothermal Method; NANOPARTICLES; LIFETIME; SENSOR; LUMINESCENCE; THERMOMETRY; EMISSION; ER3+;
D O I
10.1166/jnn.2014.8010
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pure beta-NaYF4:0.8%Pr3+ powder sample was synthesized by the hydrothermal method. The temperature dependence of the fluorescence intensity ratio (FIR) of emission bands corresponding to the P-3(1) -> H-3(5) and P-3(0) -> H-3(5) transitions was measured in the temperature range of 120 K to 300 K excited by a 473 nm continuous wave (CW) laser. The dependence of the FIR on temperature is well fitted with an exponential function and the effective energy difference obtained is 457 cm 1, which gives further an absolute temperature sensitivity of 0.01352 K-1 at 300 K. The monotonous increase of FIR with temperature and high absolute temperature sensitivity demonstrate that this material can be used as temperature sensor. In addition, mono-dispersed NaYF4:1%Pr3+ nanoparticles were also synthesized.
引用
收藏
页码:3739 / 3742
页数:4
相关论文
共 20 条
[1]   Lanthanide-based luminescent molecular thermometers [J].
Brites, Carlos D. S. ;
Lima, Patricia P. ;
Silva, Nuno J. O. ;
Millan, Angel ;
Amaral, Vitor S. ;
Palacio, Fernando ;
Carlos, Luis D. .
NEW JOURNAL OF CHEMISTRY, 2011, 35 (06) :1177-1183
[2]   Optical High Temperature Sensor Based on Enhanced Green Upconversion Emissions in Er3+-Yb3+-Li+ Codoped TiO2 Powders [J].
Cao, B. S. ;
He, Y. Y. ;
Sun, Y. ;
Song, M. ;
Dong, B. .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2011, 11 (11) :9899-9903
[3]   Optical temperature sensing through extraordinary enhancement of green up-conversion emissions for Er-Yb-Mo:Al2O3 [J].
Dong, B. ;
Cao, B. S. ;
Feng, Z. Q. ;
Wang, X. J. ;
He, Y. Y. .
SENSORS AND ACTUATORS B-CHEMICAL, 2012, 165 (01) :34-37
[4]   The unusual temperature dependence of the Eu2+ fluorescence lifetime in CaF2 crystals [J].
Duan, CK ;
Meijerink, A ;
Reeves, RJ ;
Reid, MF .
JOURNAL OF ALLOYS AND COMPOUNDS, 2006, 408 :784-787
[5]   Upconverting Nanoparticles for Nanoscale Thermometry [J].
Fischer, Lorenz H. ;
Harms, Gregory S. ;
Wolfbeis, Otto S. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (20) :4546-4551
[6]   An Effective Polymer Cross-Linking Strategy To Obtain Stable Dispersions of Upconverting NaYF4 Nanoparticles in Buffers and Biological Growth Media for Biolabeling Applications [J].
Jiang, Guicheng ;
Pichaandi, Jothirmayanantham ;
Johnson, Noah J. J. ;
Burke, Robert D. ;
van Veggel, Frank C. J. M. .
LANGMUIR, 2012, 28 (06) :3239-3247
[7]   Temperature sensor based on the Er3+ green upconverted emission in a fluorotellurite glass [J].
Leon-Luis, Sergio F. ;
Rodriguez-Mendoza, Ulises R. ;
Lalla, Emmanuel ;
Lavin, Victor .
SENSORS AND ACTUATORS B-CHEMICAL, 2011, 158 (01) :208-213
[8]   Optical temperature sensor through infrared excited blue upconversion emission in Tm3+/Yb3+ codoped Y2O3 [J].
Li, Dongyu ;
Wang, Yuxiao ;
Zhang, Xueru ;
Yang, Kun ;
Liu, Lu ;
Song, Yinglin .
OPTICS COMMUNICATIONS, 2012, 285 (07) :1925-1928
[9]   Intracellular temperature mapping with a fluorescent polymeric thermometer and fluorescence lifetime imaging microscopy [J].
Okabe, Kohki ;
Inada, Noriko ;
Gota, Chie ;
Harada, Yoshie ;
Funatsu, Takashi ;
Uchiyama, Seiichi .
NATURE COMMUNICATIONS, 2012, 3
[10]   Electronic spectra and crystal field analysis of Yb2+ in SrCl2 [J].
Pan, Zaifa ;
Duan, Chang-kui ;
Tanner, Peter A. .
PHYSICAL REVIEW B, 2008, 77 (08)