Preparation and properties of styrene butadiene rubber/natural rubber/organo-bentonite nanocomposites prepared from latex dispersions

被引:60
作者
Gu, Zheng [1 ,2 ,3 ]
Song, Guojun [3 ]
Liu, Weisheng [1 ,2 ]
Li, Peiyao [3 ]
Gao, Li [3 ]
Li, Hanhua [3 ]
Hu, Xiong [1 ,2 ]
机构
[1] Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China
[2] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
[3] Qingdao Univ, Inst Polymer Mat, Qingdao 266071, Peoples R China
基金
中国国家自然科学基金;
关键词
Nanocomposites; Emulsion intercalation; Styrene butadiene rubber (SBR); Natural rubber (NR); TGA; Swelling behavior; CLAY AQUEOUS SUSPENSION; SILICATE NANOCOMPOSITES; RUBBER; BLENDS;
D O I
10.1016/j.clay.2009.08.010
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Styrene butadiene rubber (SBR)/natural rubber (NR)/organo-bentonite nanocomposites were prepared from emulsions. The structure of the nanocomposites was characterized by TEM and XRD. The effect of organo-bentonite on the mechanical properties, thermal stability and swelling behavior was investigated. TEM and XRD confirmed that rubber chains were intercalated into the organo-montmorillonite particles. When the organo-bentonite content was lower than 12 mass%, the nanocomposites showed excellent mechanical properties. The addition of a small amount of OMMT greatly improved thermal stability and swelling behavior, which was attributed to the good barrier properties of the dispersed and partially exfoliated organo-montmorillonite particles. Organo-bentonite addition had little effect on the score and cure times of the nanocomposites, while increased the maximum and minimum torque. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:241 / 244
页数:4
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