Progress on Modified Calcium Oxide Derived Waste-Shell Catalysts for Biodiesel Production

被引：34

作者：

Ooi, Hui Khim ^{[1
]}

Koh, Xin Ning ^{[1
]}

Ong, Hwai Chyuan ^{[2
]}

Lee, Hwei Voon ^{[3
]}

Mastuli, Mohd Sufri ^{[4
,5
]}

Taufiq-Yap, Yun Hin ^{[6
,7
]}

Alharthi, Fahad A. ^{[8
]}

Alghamdi, Abdulaziz Ali ^{[8
]}

Mijan, Nurul Asikin ^{[1
]}

机构：

[1] Univ Kebangsaan Malaysia, Fac Sci & Technol, Chem Sci, Bangi 43600, Selangor, Malaysia

[2] Univ Technol, Fac Engn & Informat Technol, Sch Informat Syst & Modelling, Sydney, NSW 2007, Australia

[3] Univ Malaya, Nanotechnol & Catalysis Res Ctr NanoCat, Inst Adv Studies, Kuala Lumpur 50603, Selangor, Malaysia

[4] Univ Teknol MARA, Fac Appl Sci, Sch Chem & Environm, Shah Alam 40450, Selangor, Malaysia

[5] Univ Teknol MARA, Ctr Funct Mat & Nanotechnol, Inst Sci, Shah Alam 40450, Selangor, Malaysia

[6] Univ Malaysia Sabah, Fac Sci & Nat Resources, Kota Kinabalu 88400, Sabah, Malaysia

[7] Univ Putra Malaysia, Fac Sci, Catalysis Sci & Technol Res Ctr PutraCat, Upm Serdang 43400, Selangor, Malaysia

[8] King Saud Univ, Chem Dept, Sci Coll, POB 2455, Riyadh 11451, Saudi Arabia

来源：

CATALYSTS | 2021年 / 11卷 / 02期

关键词：

biodiesel; transesterification; waste-shell; heterogenous catalyst; green catalyst; alternative fuel;

D O I：

10.3390/catal11020194

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The dwindling of global petroleum deposits and worsening environmental issues have triggered researchers to find an alternative energy such as biodiesel. Biodiesel can be produced via transesterification of vegetable oil or animal fat with alcohol in the presence of a catalyst. A heterogeneous catalyst at an economical price has been studied widely for biodiesel production. It was noted that various types of natural waste shell are a potential calcium resource for generation of bio-based CaO, with comparable chemical characteristics, that greatly enhance the transesterification activity. However, CaO catalyzed transesterification is limited in its stability and studies have shown deterioration of catalytic reactivity when the catalyst is reused for several cycles. For this reason, different approaches are reviewed in the present study, which focuses on modification of waste-shell derived CaO based catalyst with the aim of better transesterification reactivity and high reusability of the catalyst for biodiesel production. The catalyst stability and leaching profile of the modified waste shell derived CaO is discussed. In addition, a critical discussion of the structure, composition of the waste shell, mechanism of CaO catalyzed reaction, recent progress in biodiesel reactor systems and challenges in the industrial sector are also included in this review.

引用

页码：1 / 26

页数：26

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