(2,2′-Bipyridine-κ2N,N′)bis(N-ethyl-N-methyldithiocarbamato-κ2S,S′)zinc(II)

被引：1
|
作者：
Ghafar, Noorul Aisyah Abdul [2 ]
Baba, Ibrahim [2 ]
Yamin, Bohari M. [2 ]
Ng, Seik Weng [1 ]
机构：
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Univ Kebangsaan Malaysia, Sch Chem Sci, Bangi 43600, Malaysia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
CRYSTAL-STRUCTURE; 2,2'-BIPYRIDINE ADDUCTS; 1,10-PHENANTHROLINE; ZINC(II);
D O I：
10.1107/S1600536810002606
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The complete molecule of the title compound, [Zn(C4H8NS2)(2)(C10H8N2)], is generated by crystallographic twofold symmetry, with the Zn atom lying on the rotation axis; the axis also bisects the central C-C bond of the 2,2'-bipyridine molecule. The metal atom is chelated by two S,S'-bidentate dithiocarbamate anions and the N,N'-bidentate heterocycle, resulting in a distorted cis-ZnN2S4 octahedral geometry. The methyl and ethyl groups of the anion are statistically disordered.
引用
收藏
页码：M208 / U1129
页数：8
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