Three-membered-ring-based molecular architectures

被引：127
作者：
de Meijere, Armin [1 ]
Kozhushkov, Sergei I. [1 ]
Schill, Heiko [1 ]
机构：
[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
来源：
CHEMICAL REVIEWS | 2006年 / 106卷 / 12期
关键词：
D O I：
10.1021/cr0505369
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An overview is given of the wonderful world of molecular assemblies containing more than one cyclopropane ring. Topics covered include linear aggregates of cyclopropane rings, branched aggregates of three-membered rings and cage structures with three-membered rings. The first covers 1,2-linked oligocyclopropyl systems, oligocyclopropenyl systems, fused systems, 1-1-linked oligocyclopropyl systems and spiroannelated systems-linear triangulanes and heteroanalogues. The second includes oligocyclopropyl-substituted carbo- and heterocycles, branched triangulanes and heteroanalogues, oligospirocyclopropanated carbo- and heterocycled as well as cyclic triangulanes. Finally, the last one focuses on cages incorporating three-membered rings, cages and half-cages with annelated three-membered rings, cages with spiroannelated three-membered rings and cages with three-membered ring substituents.
引用
收藏
页码：4926 / 4996
页数：71
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