Three-membered-ring-based molecular architectures

被引：127

作者：

de Meijere, Armin ^{[1
]}

Kozhushkov, Sergei I. ^{[1
]}

Schill, Heiko ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

来源：

CHEMICAL REVIEWS | 2006年 / 106卷 / 12期

关键词：

D O I：

10.1021/cr0505369

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview is given of the wonderful world of molecular assemblies containing more than one cyclopropane ring. Topics covered include linear aggregates of cyclopropane rings, branched aggregates of three-membered rings and cage structures with three-membered rings. The first covers 1,2-linked oligocyclopropyl systems, oligocyclopropenyl systems, fused systems, 1-1-linked oligocyclopropyl systems and spiroannelated systems-linear triangulanes and heteroanalogues. The second includes oligocyclopropyl-substituted carbo- and heterocycles, branched triangulanes and heteroanalogues, oligospirocyclopropanated carbo- and heterocycled as well as cyclic triangulanes. Finally, the last one focuses on cages incorporating three-membered rings, cages and half-cages with annelated three-membered rings, cages with spiroannelated three-membered rings and cages with three-membered ring substituents.

引用

页码：4926 / 4996

页数：71

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