Organometallics meet colloid chemistry: A case study in three phases based on molecular carbonyl precursors containing zinc and manganese

被引：33
作者：
Orlov, A.
Roy, A.
Lehmann, M.
Driess, M.
Polarz, S.
机构：
[1] Tech Univ Berlin, D-10623 Berlin, Germany
[2] Univ Duisburg Gesamthsch, D-47057 Duisburg, Germany
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 02期
关键词：
D O I：
10.1021/ja0659626
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two organometallic compounds containing zinc and manganese in different ratios are used as single-source precursors for the preparation of various new, bimetallic oxide materials with nanoscaled dimensions. It is shown that the materials synthesis can be performed in the solid-state, the liquid-phase, and even in the gas-phase. The molecular composition of the precursors determines the composition of the resulting materials. In addition, two novel methods for the preparation of highly crystalline metal oxide colloids are presented: The coupling between a gas-phase process and a colloidal approach, and the application of ozone as an oxidant for the transformation of metal carbonyls into oxides in the liquid phase.
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收藏
页码：371 / 375
页数：5
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