Dynamical behavior and dipole-dipole interactions of tetrafluoromethane-water

被引：49

作者：

Caminati, Walther ^{[1
]}

Maris, Assimo ^{[1
]}

Dell'Erba, Adele ^{[1
]}

Favero, Paolo G. ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 40期

关键词：

hydrophobic interactions; molecular complexes; molecular dynamics; rotational spectroscopy; supersonic jets;

D O I：

10.1002/anie.200602000

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Top stuff: The configuration of tetrafluoromethane-water is driven by dipole-dipole interactions rather than hydrogen bonds. The complex, which consists of a planar and a spherical moiety, is an asymmetric top in its equilibrium conformation, but its effective behavior is that of a symmetric top, owing to its high internal dynamics. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：6711 / 6714

页数：4

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