Significance of carbon additive in negative lead-acid battery electrodes

被引:83
作者
Calabek, M.
Micka, K. [1 ]
Krivik, P.
Baca, P.
机构
[1] J Heyrovsky Inst Phys Chem, Prague 18223 8, Czech Republic
[2] Brno Tech Univ, Fac Elect Engn & Commun, Brno 61600, Czech Republic
关键词
negative lead battery electrode; cycle life; graphite additive; titanium dioxide additive;
D O I
10.1016/j.jpowsour.2005.11.022
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
improvement of the cycle life of negative lead-acid battery electrodes in the partial state of charge regime can be achieved not only by the addition of graphite to the active mass but also by the addition of titanium dioxide. The experimental results have been attributed to hindrance of the crystal growth of lead sulfate deposited in the electrode pores. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:864 / 867
页数:4
相关论文
共 16 条
[1]  
[Anonymous], P ADV LEAD AC BATT
[2]  
CALABEK M, 1997, AMC10 ALABC
[3]  
CALABEK M, 1966, J POWER SOURCES, V62, P161
[4]   Progress in overcoming the failure modes peculiar to VRLA batteries [J].
Cooper, A ;
Moseley, PT .
JOURNAL OF POWER SOURCES, 2003, 113 (02) :200-208
[5]   FAILURE MODES OF LEAD-ACID-BATTERIES [J].
CULPIN, B ;
RAND, DAJ .
JOURNAL OF POWER SOURCES, 1991, 36 (04) :415-438
[6]   THE ELECTROCHEMISTRY OF THE POROUS LEAD ELECTRODE IN SULFURIC-ACID - A SELECTIVE REVIEW [J].
HAMPSON, NA ;
LAKEMAN, JB .
JOURNAL OF POWER SOURCES, 1981, 6 (02) :101-120
[7]  
Hollenkamp A.F., 2001, N12 ALABC
[8]  
LAM LT, 2002, 20 ALABC
[9]  
LAM LT, 2004, 9ELBC BERL SEPT
[10]   THEORY OF POROUS-ELECTRODES .15. LEAD-ACID CELL [J].
MICKA, K ;
ROUSAR, I .
ELECTROCHIMICA ACTA, 1976, 21 (08) :599-603