Pyridine and phosphine reactions with [CPh3][B(C6F5)4]

被引：64

作者：

Cabrera, Lourdes ^{[1
]}

Welch, Gregory C. ^{[1
]}

Masuda, Jason D. ^{[1
]}

Wei, Pingrong ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 09期

基金：

加拿大自然科学与工程研究理事会;

关键词：

trityl borate; Lewis acid-base interaction; nucleophilic aromatic substitution;

D O I：

10.1016/j.ica.2006.02.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trityl borate salts [4-RPyCPh3][B(C6F5)(4)] (R = H 1, Bu-t 2, Et 3, NMe2 4) and [R3PCPh3][B(C6F5)(4)] (R = Me 5, Bu-n 6, Ph[1] 7, p-MeC6H4 8) are readily prepared via equimolar reaction of the appropriate pyridine or phosphine and trityl borate [CPh3][B(C6F5)(4)]. The analogous reactions of (PPr3)-Pr-i affords the product [(p-(Pr3P)-Pr-i-C6H4)Ph2CH][B(C6F5)(4)] (9) while the corresponding reactions of Cy3P and (Bu3P)-Bu-t gave the cyclohexadienyl derivatives [(p-R3PC6H5)CPh2][B(C6F5)(4)] (R = Cy 10, Bu-t 11). X-ray structures of 5 and 9 are reported. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：3066 / 3071

页数：6

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