An organic cation as a silver(I) analogue for the arylation of sp2 and sp3 C-H bonds with iodoarenes

被引：100

作者：

Arroniz, Carlos ^{[1
,2
]}

Denis, J. Gabriel ^{[1
]}

Ironmonger, Alan ^{[2
]}

Rassias, Gerasimos ^{[2
]}

Larrosa, Igor ^{[1
]}

机构：

[1] Queen Mary Univ London, Sch Biol & Chem Sci, London E1 4NS, England

[2] GlaxoSmithKline Med Res Ctr, Stevenage SG1 2NY, Herts, England

来源：

CHEMICAL SCIENCE | 2014年 / 5卷 / 09期

基金：

欧洲研究理事会; 英国工程与自然科学研究理事会;

关键词：

CATALYZED DIRECT ARYLATION; ROOM-TEMPERATURE; COUPLING REACTIONS; PALLADIUM; ACTIVATION; CARBON; FUNCTIONALIZATION; FLUORENONES; OXIDANT; DERIVATIVES;

D O I：

10.1039/c4sc01215a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions promoted by stoichiometric amounts of silver salts suffer from high cost, limited availability and raise environmental concerns. This manuscript describes studies leading to the discovery of a general replacement for silver with an inexpensive and convenient organic salt in palladium catalyzed direct C(sp(2))-H and C(sp(3))-H arylation reactions.

引用

页码：3509 / 3514

页数：6

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