Synthesis, EPR and ENDOR of [60]fulleropyrrolidine bisadducts with nitroxide addends: Magnitude and sign of the exchange interaction

被引：0

作者：

Mazzoni, M

Franco, L

Corvaja, C

Zordan, G

Menna, E

Scorrano, G

Maggini, M

机构：

[1] Univ Padua, Dipartimento Chim Fis, I-35131 Padua, Italy

[2] Univ Padua, Dipartimento Chim Organ, CNR, CMRO, I-35131 Padua, Italy

来源：

CHEMPHYSCHEM | 2002年 / 3卷 / 06期

关键词：

ENDOR spectroscopy; EPR spectroscopy; exchange interactions; fullerenes; nitroxide radicals;

D O I：

10.1002/1439-7641(20020617)3:6<527::AID-CPHC527>3.0.CO;2-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The magnitude and sign of the electron exchange interaction J between two nitroxide radicals in a series of [60]fullerene bisadducts (trans-4 bisadduct shown) have been measured. The J value correlates with the distance between and the relative orientation of the unpaired electron molecular orbitals.

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页码：527 / +

页数：6

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