Vapor-liquid equilibrium for binary system of 1-propanethiol, thiophene, and diethyl sulfide with toluene at 90.03 kPa

被引:9
作者
Erlin, Sapei
Zaytseva, Anna
Uusi-Kyyny, Petri
Younghun, Kim
Keskinen, Kari I.
Aittamaa, Juhani
机构
[1] Aalto Univ, Dept Chem Technol, FI-02015 Helsinki, Finland
[2] Neste Jacobs Oy, FI-06101 Porvoo, Finland
关键词
D O I
10.1021/je060093l
中图分类号
O414.1 [热力学];
学科分类号
摘要
Isobaric vapor-liquid equilibrium (VLE) for three systems with different organic sulfur compounds (1-propanethiol + toluene, thiophene + toluene, and diethyl sulfide + toluene) were measured at 90.03 kPa with a circulation still. The experimental results were compared with original UNIFAC, UNIFAC-Dortmund, and COSMO-RS predictive models. All systems showed nearly ideal behavior. VLE data sets measured passed the point consistency test.
引用
收藏
页码:1372 / 1376
页数:5
相关论文
共 26 条
[21]   VAPOR PRESSURES AND BOILING POINTS OF SOME PARAFFIN, ALKYLCYCLOPENTANE, ALKYLCYCLOHEXANE, AND ALKYLBENZENE HYDROCARBONS [J].
WILLINGHAM, CB ;
TAYLOR, WJ ;
PIGNOCCO, JM ;
ROSSINI, FD .
JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS, 1945, 35 (03) :219-244
[23]   Prediction of phase equilibria and excess properties for systems with sulfones [J].
Wittig, R ;
Lohmann, J ;
Gmehling, J .
AICHE JOURNAL, 2003, 49 (02) :530-537
[24]   Vapor-liquid equilibria by UNIFAC group contribution. 6. Revision and extension [J].
Wittig, R ;
Lohmann, J ;
Gmehling, J .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (01) :183-188
[25]  
Yaws C. L., 1999, CHEM PROPERTIES HDB
[26]   VAPOR-LIQUID EQUILIBRIUM DETERMINATION BY A NEW APPARATUS [J].
YERAZUNIS, S ;
PLOWRIGHT, JD ;
SMOLA, FM .
AICHE JOURNAL, 1964, 10 (05) :660-665