Connecting micelles by metallo-supramolecular interactions: towards stimuli responsive hierarchical materials

被引：52

作者：

Guillet, Pierre ^{[1
]}

Mugemana, Clement ^{[1
]}

Stadler, Florian J. ^{[2
]}

Schubert, Ulrich S. ^{[3
,4
]}

Fustin, Charles-Andre ^{[1
]}

Bailly, Christian ^{[2
]}

Gohy, Jean-Francois ^{[1
,3
,4
]}

机构：

[1] Univ Catholique Louvain, Unite Chim Mat Inorgan & Organ CMAT, B-1348 Louvain, Belgium

[2] Univ Catholique Louvain, Unite Phys & Chim Hauts Polymeres POLY, B-1348 Louvain, Belgium

[3] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands

[4] Dutch Polymer Inst, NL-5600 MB Eindhoven, Netherlands

来源：

SOFT MATTER | 2009年 / 5卷 / 18期

关键词：

BLOCK-COPOLYMERS; GELS; NANOPARTICLES;

D O I：

10.1039/b910325b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel strategy to link block copolymer micelles via metal-ligand interactions, leading to hierarchical supramolecular networks is presented. The mechanical properties of the obtained materials can be tuned easily by the choice of the metal ions used. The strong networks exhibit a chemical and mechanical stimuli responsive behavior, with almost instantaneous recovery in the latter case.

引用

页码：3409 / 3411

页数：3

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